A new iron age?

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Iron and steel: The billion-ton business

We may call this the age of information, but we could also call it the age of steel. More than 1.5 billion tons of steel are made each year for bridges, concrete reinforcement, vehicles and building frameworks, among many other purposes.

Huge steel arch rises over road with cables connected from top of arch to roadway.

The Hulme Arch Bridge, at Hulme, Manchester, England, is a harmonious construction of steel cables and arches.

Steel is usually about 99 percent iron, and the tight bond between iron and oxygen in iron ore explains much of the environmental cost of making steel.

Now MIT professor Donald Sadoway has found a way to sidestep many of these drawbacks with a 1565° C process that uses electricity to separate iron and oxygen.

A backward battery

Electrolysis is the reverse of a battery. Both batteries and electrolytic cells contain an electrolyte that conducts electricity between two electrodes. In both cases, the process alters the chemistry of the electrolyte, and an electrical current flows.

In a battery, chemical energy in the electrolyte is converted to electrical energy. In electrolysis, electrical energy is converted into chemical energy.

Photos from the electric smelter

Top: Coarse crystal texture atop finer texture; bottom: clean, square metal electrode is next to one draped in black gooky material.

Photo: Donald Sadoway/Nature
Top: On the cathode, chunky, molten iron sits on top of cathode material. Bottom left: The chromium-iron anode before use. Bottom right: After use, the anode is almost the same size, though it’s covered with cooled electrolyte made of iron and iron ore.

In iron electrolysis, reduction — the chemical reaction that allows iron to release oxygen — occurs at an electrode called the anode. Nearly pure iron pools at the other electrode.

In conventional iron smelting, the oxygen reacts with carbon in coke, a carbon fuel, to make carbon dioxide. The molten iron is brittle, due to a high carbon content, so a second step is needed to drive off that carbon.

Both processes make carbon dioxide pollution.

Coke, a fuel used to strip oxygen from iron ore, was made in this English coke oven. Rollover to see air being blown through molten iron to clear carbon leftover from the coke. This Bessemer process is no longer used, but impurities remain a hindrance in steelmaking.
Credit 1: Earthwatcher, (rollover) 2: Republic Steel, Youngstown, Ohio, Wikimedia Commons

Because the energy to cut the bond between iron and oxygen — and much of the electricity used to refine steel — both originate in coal, the iron and steel sector is “the second-largest industrial user of energy ‚Ķ and the largest industrial source of CO2¬†emissions,” according to the International Energy Agency.

By improving efficiency, the new process should cut down on greenhouse gases. However, although because electricity is still needed, the size of the benefit depends on how the current is generated.

Still, the process can, judo-style, convert the oxygen in iron ore from a liability into an asset. “Oxygen bubbles float to the top, and you can collect them,” says Sadoway. “You are making, for every ton of iron, two-thirds of a ton of oxygen that’s industrial quality, marketable.”

Amazing anode

The critical advance is an anode made of chromium and iron that can survive a 2850°F, oxygen-rich process — conditions conducive to a chemical reaction that would obliterate most materials.

Instead, a thin film of metal oxide forms on the anode in the intense heat. “It’s remarkable,” says Sadoway. The oxide, he says, “forms a protective layer that prevents further consumption of the base metal — yet at the same time, is not resistive to any great extent.”

That allows an electric current to enter the hot brew of iron oxide.

Hurdles remain. “I am not saying anybody will take a wrecking ball to an integrated steel plant,” Sadoway says. But he thinks an electrolytic smelter could avoid the need for a sinter plant to process iron ore, a coke oven to produce coke, and an oxygen furnace to remove excess carbon left over from the coke.

Thin silver metal rods grouped together and lying horizontally.

Huge tonnages of steel reinforcing rods are used to strengthen concrete.

Steel plants cost billions of dollars, and must produce a couple of million tons per year to make money, Sadoway says. If the electrolytic process, with its reduced need for fossil fuel and equipment, survives further testing, smaller plant expansions could be possible, he says.

Any climate-based restrictions on carbon dioxide pollution will only help the new process become a player in the giant steel industry, Sadoway says. “We are hoping there will be early adopters,” he says, “if the price point is lower and there is an environmental imperative toward clean steelmaking.”

– David J. Tenenbaum

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Terry Devitt, editor; Emily Eggleston, project assistant; S.V. Medaris, designer/illustrator; David J. Tenenbaum, feature writer; Amy Toburen, content development executive

Bibliography

  1. A new anode material for oxygen evolution in molten oxide electrolysis, Antoine Allanore, Lan Yin & Donald R. Sadoway, Nature, 10 May 2013.
  2. Steel: from start to finish
  3. Environmental Protection Agency on iron and steel
  4. The story of steel in China
  5. Nitty gritty details about how to reduce steel production emissions